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Problem 15

Which of the following are coloured due to charge transfer spectra (a) \(\mathrm{CrO}_{3}\) (b) \(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right) \mathrm{NO}\right] \mathrm{SO}_{4}\) (c) \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) (d) All of these

Problem 17

For which lanthanide are \(+2\) and \(+3\) oxidation states are common? (a) Eu (b) \(\mathrm{Na}\) (c) \(\mathrm{Ce}\) (d) \(\mathrm{La}\)

Problem 18

An alkaline solution of ___ and citrate ions is called ___. (a) silver chloride; Tollen's reagent (b) cupric sulphate; Benedict's solution (c) silver nitrate; Fehling's solution (d) cupric sulphate; Schiff's reagents

Problem 19

Ferrous ion changes to \(\mathrm{X}\) ion, on reacting with acidified hydrogen peroxide. The number of d-electrons present in \(\mathrm{X}\) and its magnetic moment (in B.M.) are respectively (a) 5 and \(4.9\) (b) 4 and \(5.92\) (c) 6 and \(6.95\) (d) 5 and \(5.92\)

Problem 20

Which one of the following characteristics of the transition metal is associated with their catalytic activity? (a) variable oxidation states (b) colour of hydrated ions (c) paramagnetic behaviour (d) high enthalpy of atomization

Problem 21

Iron loses its magnetic property at (a) melting point (b) curie point (c) \(1000 \mathrm{~K}\) (d) boiling point

Problem 22

In the extraction of zinc, the formation of blue flame is due to the burning of (a) \(\mathrm{C}\) (b) \(\mathrm{CO}\) (c) \(\mathrm{Zn}\) (d) \(\mathrm{ZnO}\)

Problem 23

Which one of the following ions exhibits colour in aqueous solution? (a) \(\mathrm{Ti}^{4+}\) (b) \(\mathrm{Zn}^{2+}\) (c) \(\mathrm{Ni}^{2+}\) (d) \(\mathrm{Sc}^{3+}\)

Problem 25

Which one of the following ions is colourless in its aqueous solution? (a) \(\mathrm{Ti}^{3+}\) (b) \(\mathrm{Cu}^{2+}\) (c) \(\mathrm{Ni}^{2+}\) (d) \(\mathrm{Zn}^{2+}\)

Problem 26

Which one of the following ions exhibit highest magnetic moment? (a) \(\mathrm{Cu}^{2+}\) (b) \(\mathrm{Ti}^{3+}\) (c) \(\mathrm{Ni}^{2+}\) (d) \(\mathrm{Mn}^{2+}\)

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