Chapter 8: 7P (page 243)
Some bacteria produce thiosugars, which contain a C—S covalent bond, such as 2-deoxy-2-thio-β-D-glucose. Draw the structure of this sugar.
Short Answer
The structure of the sugar is:
Chapter 8: 7P (page 243)
Some bacteria produce thiosugars, which contain a C—S covalent bond, such as 2-deoxy-2-thio-β-D-glucose. Draw the structure of this sugar.
The structure of the sugar is:
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Get started for freeGlycogen is treated with dimethyl sulfate, which adds a methyl group to every free OH group. Next, the molecule is hydrolyzed to break all the glycosidic bonds between glucose residues. The reaction products are then chemically analyzed. (a) How many different types of methylated glucose molecules are obtained? (b) Draw the structure of the one that is most abundant.
Some bacterial signaling systems involve kinases that transfer a phosphoryl group to a His side chain. Draw the phospho-His side chain.
Calculate the chemical potential difference when intracellular [Na+] = 10 mM and extracellular [Na+] = 150 mM at 37°C. (b) What would the electrochemical potential be if the membrane potential were -60 mV (inside negative)?
Explain why a sugar can form at least two different glycosides.
During gel electrophoresis, glycoproteins migrate as relatively diffuse bands, whereas nonglycosylated proteins typically migrate as narrow, well-defined bands. Explain the difference in electrophoretic behaviour.
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