Chapter 2: Problem 13
\(\mathrm{A}(\mathrm{n}) \) ________ can help keep the \(\mathrm{pH}\) of a solution stable. a. covalent bond b. hydrogen bond c. buffer d. \(\mathrm{pH}\)
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
pH stability
Buffers play a key role in maintaining pH stability. They do so by absorbing excess hydrogen ions (H+) when the solution becomes too acidic and donating them back when it becomes too basic. This buffering action happens because buffers usually consist of a weak acid and its conjugate base, which can interchange protons according to the surrounding concentration of H+ ions.
A stable pH is vital for:
- Maintaining enzyme activity: Enzymatic reactions often have an optimal pH range.
- Ensuring cellular function: Cells require a consistent pH to function correctly.
- Supporting metabolic processes: Many metabolic pathways depend on specific pH conditions.
acid-base balance
The significance of acid-base balance is often highlighted in biological contexts, such as within the human body. The human body, for example, operates optimally at a relatively constant pH of around 7.4. To maintain this balance, physiological systems use buffers like bicarbonate to neutralize excess acids or bases.
Within the scope of chemistry, the importance of buffers in managing acid-base balance cannot be overstated. A buffer solution consists typically of a weak acid and its conjugate base, or a weak base and its conjugate acid. Here's how they work:
- When an acid is added, the conjugate base in the buffer solution will neutralize it, preventing pH changes.
- Conversely, when a base is added, the weak acid will neutralize the base, again maintaining the pH.
chemical equilibrium
In the context of buffers, chemical equilibrium is crucial as buffers maintain their ability to stabilize pH by establishing equilibrium between the weak acid and its conjugate base or vice versa. This equilibrium enables the solution to absorb or release hydrogen ions without significant shifts in pH.
The principle of Le Chatelier also plays a vital role here, stating that if a system at equilibrium is disturbed, it will shift to minimize that disturbance. For example:
- When extra H+ ions are added to a buffer, the equilibrium shifts to consume these ions, minimizing changes in pH.
- When OH- ions are introduced, the buffer provides H+ ions from its acidic component to balance the increase in base.