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People often say things like "A city has reached equilibrium size" or "A person has reached equilibrium between needs and wants." Discuss whether these uses of equilibrium are compatible with the word's thermodynamic meaning.

Short Answer

Expert verified
The term equilibrium, in everyday language and thermodynamics, shares the idea of balance and stability. However, while thermodynamics implies a system with no further changes, everyday usage of equilibrium implies stability over time, but not necessarily the absence of change.

Step by step solution

01

Understanding the Thermodynamic Meaning of Equilibrium

Firstly, understand that in thermodynamics, equilibrium refers to the state in which a system is in balance. This means that all acting influences are canceled by others resulting in a stable, unchanging system. A system in equilibrium will experience no changes over time.
02

Analyzing Everyday Usage of Equilibrium

Ordinary language often uses the term equilibrium to describe a balance between different factors. For instance, saying a city has reached an equilibrium size means that its size has stabilized due to the balance between factors such as birth rate, death rate, immigration, and emigration. Similarly, an equilibrium between a person's needs and wants implies a state where the person’s needs and wants are in balance with their resources.
03

Comparing Both Meanings

Compare these two usage contexts. Both share the idea of a balance where factors counteract each other to reach stability. However, a key difference is that in thermodynamics, equilibrium implies a system in which no further changes occur. In everyday usage, it is not as strict. A city's size or a person's needs may still change over time, but the term equilibrium is used when the changes become stable or predictable over time.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Equilibrium State
In thermodynamics, an equilibrium state is a situation where a system is perfectly balanced. All the forces and influences acting on it cancel each other out, leading to a stable condition where no changes occur over time. This is why thermodynamic equilibrium is considered static. Changes might attempt to happen, but the equilibrium prevents them from manifesting.

In the context of everyday language, equilibrium also describes balance. However, this usage can be more dynamic. For instance, when we talk about a city's equilibrium size, we're referring to a balance of growth factors, like birth and death rates, but not necessarily a completely static state. In daily terms, equilibrium encompasses conditions where changes might still happen but at a predictable or balanced pace.
Thermodynamics
Thermodynamics is a branch of physics dedicated to understanding the relationships among heat, energy, and work in a system. It focuses on how energy changes form and how it affects matter. The discipline consists of several laws that explain how energy and matter interchange and impact each other, especially in terms of energy transfer and how it drives changes in a thermodynamic system.

A crucial aspect of thermodynamics is the study of equilibrium states. These are reached when the system achieves maximum entropy and no energy differences drive further changes. However, it's critical to note that thermodynamics' laws only apply to systems capable of being isolated for precise study.
Balance in Systems
Balance in systems is a broad concept that applies to various disciplines, beyond just physics. In terms of thermodynamics, balance is achieved when all elements within a system operate in harmony, prohibiting any fluctuations that could lead to change.

In more general terms, balance often refers to a state where multiple factors influence a situation, but their combinations lead to a steady condition. Whether it’s a city stabilizing in size or a person's financial stability, balance indicates some form of regularity despite the potential for external changes. This kind of balance can sometimes mimic the static nature observed in thermodynamic equilibrium but allows for gradual, predictable change.
Thermodynamic Principles
The principles of thermodynamics explain not just how energy is transferred, but also how systems react to these exchanges. The fundamental principles include notable laws:

  • The Zeroth Law, establishing thermal equilibrium and allowing temperature as a fundamental property.
  • The First Law, the conservation of energy principle, indicating energy cannot be created or destroyed.
  • The Second Law, which introduces the concept of entropy, highlighting that energy naturally disperses or spreads out if not hindered.
  • The Third Law, which deals with reaching absolute zero temperature where entropy would theoretically minimize.
These principles clarify why in thermodynamics, equilibrium states must entail no spontaneous changes. Each law contributes to a deeper understanding of how systems resist evolving to maintain a state of thermodynamic equilibrium.

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Most popular questions from this chapter

Amphibian eggs laid in freshwater exhibit low water permeabilities and thus do not swell and burst osmotically. When investigators first believed they had identified an aquaporin, they manipulated amphibian eggs so the eggs expressed the purported aquaporin protein. When the investigators observed those eggs swell and burst, they knew they had made a monumental discovery: They had found the first aquaporin. Recalling what we have discussed regarding red blood cells, explain why this experiment provided convincing evidence for channel-mediated water transport.

The cell membranes of mammalian red blood cells are permeable to urea. If red blood cells are dropped into a solution of urea that is identical in osmotic pressure (isosmotic) to the cytoplasm of the cells, although the cells do not swell and burst as quickly as when they are dropped simply into pure water, they eventually swell and burst. Explain. Also discuss how you would design a solution into which red cells could be placed without ever swelling. (Hint: Think about whether urea will stay on the outside of the cells and the implications for osmotic pressures.)

Whereas electrical currents are carried by electrons in copper wire, they are carried by ions in aqueous solutions. Explain how an active-transport mechanism can create an electrical current across a membrane.

When we discussed the microscopic mechanism of simple diffusion, we made the following point: After the concentrations of glucose on the two sides of a membrane have become equal, glucose molecules continue to move at random from left to right and from right to left; the numbers of glucose molecules going in the two directions are equal, however, explaining why the two concentrations stay equal once they have become equal. Taking advantage of the options provided by multiple isotopes of elements, how could you do an experiment, in an actual physical system, to determine whether the point we have made here is true?

Consider three groups of solutes: (1) steroid hormones, fatty acids, and other lipids; (2) inorganic ions; and (3) polar organic solutes such as glucose and amino acids. What is the principal mechanism by which each group crosses cell membranes passively? Why do members of the first group cross in a fundamentally different way from solutes belonging to the other two groups?

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